Thallium oxide is used to produce special optical components with a refractive index gradient: Thallium-Containing Optical Glass (1982), and also low softening temperature glass Mercury thallium fluorophosphate glasses (1983).
An alloy of mercury and indium containing about 14% thallium has a melting point of 23°C lower than mercury alone. This can be used in low temperature thermometers and switches: Mercury-indium-thallium alloys (1963).